pNIC	virtual Switch	Port group					pNIC conf on PG

nic0			ServiceConsole					nic0 Active/nic1 Stand By
	vSwitch1
nic4			LAN-00						nic1 Active/nic0 Stand By or nic0 and nic 1 active


nic1			VMotion (Must set VLAN ID)			NIC1 Active/NIC2 Stand by
	vSwitch2											
nic2			iSCSI (Must set VLAN ID)			NIC2 Active/NIC1 Stand by			


nic3
	vSwitch3	DMZ						NIC3 active/NIC5 Stand by or both active for load balance
nic5


Again. this is only recomendation. other solution is that you have doubled network for LAN and only single network for DMZ.
I don't know what you realy need. In perfect world you shold have every think separated and doubled.