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Scott Lowes (Mastering vSphere 4 book) - was mostly for general reference.
vReference.com - great for quick view and study of specific configuration commands and config maximums.
Thanks Andre but I am looking for an all-in-one study guide book if possible.
Remember that the official documentation is the one from VMware related to the last product version.
Also the blueprint with some notes could help:
There are some VCP4 books coming out over the next few months, although as the exam questions change over time I'm not sure how valuable those books will be. My blog is amongst the links that Andre has already posted. The key document for the VCP4 exam is the blueprint. I've also collated all the key VCP4 resources and placed them under the VCP4 menu on my Think Virtually website: http://thinkvirtually.co.uk