If you'd like to split the service console onto vmnic1, then you'll
1) Create a new virtual switch and assign vmnic1 to it (configuration \ networking \ add networking - you can then select Service Console port and on the next screen you'll be able to create a new virtual switch with vmnic1). You'll have to assign a unique IP address for the new service console port and if you're going to leave the SC port on the same subnet as the current SC subnet then you don't have to change the default gateway.
2) Once you have create the new SC port and tested it, you can delete the SC port on vSwitch0.
As an alternative, I would suggest adding vmnic1 to vswitch0 and leaving both the SC and VM ports on that vswitch. That way the failure of either vmnic0 or 1 will have not a significant impact on the host. If you're concerned about the security of having the SC port on the same vswitch, you could add a VLAN to the SC port.
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