Change to 64bit application when using start program in guest

I am trying to figure out how to get VRO to run the 64 bit version of a program versus the 32 bit.  When I have UAC on and try to run powershell.exe from c:\windows\system32\windowspowershell\v1.0\powershell.exe it defaults to running the syswow64 version instead. From there I can't seem to get it to run the system 32 bit version.  I have tried specifying the sysnative folder but still have had no success.

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