I know you can configure alarms in vCenter to watch for vReplication issues, there is a great blog post here about it. With that, you can have the alarm email you for alerting purposes.
What I'm not sure about is custom alarms in vCenter and having vROPs alert on it also, that probably needs some testing unless anyone else can comment on it.
Why do you want it in vROPs out of interest?
Thx for reply this will help a lot I think
Why do I need this ?
Its simple, vRealize Operations must be (in my opinion of course) a complex tool to monitor all infrastructure. There are packs to monitor storage, to monitor for example vCloud Director, etc. If in same case there is a failure of host with vSphere Replication Virtual Machine, after restart of this Appliance I noticed that, there is a problem with replication. So it would be great to monitor this replication and alert.