Hey Tommy,
first: Try it out, maybe the app "VMware Airwatch Admin Assistant" is broken and needs to be reinstalled.
second: To assign a configuration to an app in advance you need help from the developer, who offers you a possibility to repackage your app. For examples, see Firefox for Enterprise (https://support.mozilla.org/en-US/products/firefox-enterprise/policies-customization-enterprise).
kind regards
Benjamin
