VMware support was able to figure this out. For some reason, not all the workflows were available even though I deployed a new 6.0.3 appliance and imported the config from my previous 5.5 instan...
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VMware support was able to figure this out. For some reason, not all the workflows were available even though I deployed a new 6.0.3 appliance and imported the config from my previous 5.5 instance. So, we went into the Orchestrator Configuration webpage->Troubleshooting and clicked "Reset Current Version" for plug-ins. Bounced it and the missing workflows were there. Then, went back into Orchestrator Configuration webpage->vSphere Configuration under General and input the IP of our vCenter PSC and used administrator@vsphere.local. The look up data worked, I checked most of the boxes, and was able to see vCenter in vCO afterwards.