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If the ESXi node is running in a VM, then VMware Tools should be installed and you can use Invoke-VMScript.
If SSH is enabled on that ESXi node you could also use the Posh-Ssh module and for example the Get-ScpItem cmdlet.
Samples of both methods can be found in this community.
Blog: lucd.info Twitter: @LucD22 Co-author PowerCLI Reference