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I phrased this exact same question with exact same sources to support.
My primary goal was SQL 2012 and Server 2012 R2 as the platforms of choice for App Volumes.
As of 2.6 both SQL 2012 and Server 2012 R2 are supported platforms for App Volumes Manager
Past documentation states SQL 2008 and Server 2008 as supported platforms.
As for as Agent install it looks like Windows 7 (32/64) and Server 2008 R2 for VDI and RDSH.
As per latest Documentation: https://www.vmware.com/pdf/app-volumes-26-users-guide.pdf
or
https://www.vmware.com/support/appvolumes/doc/app-volumes-26-release-notes.html
Any other OS outside of that should be taken up with VMware support (WIndows 8 or 8.1, etc.).