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Try to install vCenter onto Windows 2008 Server because vCenter requires several components to function (or windows 2012 Server, you can use each for free for 180 days, try to install Windows Server onto another 64-bit PC/Server with at least 4GB RAM). Or you can deploy vCenter server on top of your ESXi as a virtual machine (download the vCenter appliance from vmware, then use vSphere client to import the ova appliance), after installing, you will visit the https://*.*.*.*:5480 (*.*.*.* the IP of the vCenter Virtual MAchine) and configure the vCenter, but my experience with appliance is no good. Then use vCenter web client from your windows 7 machine, you should be fine.
If you have a powerful PC, try this http://www.labguides.com, it will allow you build a sophisticated "enterprise" like datacenter. Buona fortuna!