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Why do you want to do this from CLI?
It's only clicks from GUI
Changing the virtual SCSI controller of a virtual machine (1002149) | VMware KB
PowerCLI command Set-ScsiController - vSphere PowerCLI Cmdlets Reference
Or, it's possible to power down VM and edit VM's vmx manually.
Here is difinition VMware Continuum - SCSI-controller : the parameters