hello @tjk0711 ,
Application groups in vRNI can be created in 2 ways -
refer to https://docs.vmware.com/en/VMware-vRealize-Network-Insight/5.3/Using-vRealize-Network-Insight.pdf
1. Manually (refer to steps in page 323 under the section ' Create an Application Manually ')
2. Applications can also be discovered using constructs such as Tags, VM names, CMDBs, Flows (refer to page 325 under the section 'Application Discovery')
Hope this helps.