Yes, you can do this - BUT...
1. You must use the Virtual Network Editor (which is not part of the Player installation - you must extract it from the Workstation installer - search the site for instructions).
2. Set 2 unused VMnet switches to one each physical NIC on your host.
3. In your VM configuration, set the network connection type to "Custom" and specify whichever VMnet (setup in step 2) you want the VM to connect to.