Not sure how you are going to place all datastores in the datastorecluster in maintenance mode.
On the last datastore, where will the VMs be moved to?
In any case, you can create a DSC, add datastores and place a datastore in SDRS maintenance mode with regular PowerCLI cmdlets.
See this short snippet
$datacenterName = 'MyDC'
$dsNames = 'DS1','DS2'
$dc = Get-Datacenter -Name $datacenterName
$dsc = New-DatastoreCluster -Name TempDSC -Location $dc
Get-Datastore -Name $dsNames | Move-Datastore -Destination $dsc
Get-Datastore -Name $dsNames |
Select -First 1 |
Set-Datastore -MaintenanceMode:$true -EvacuateAutomatically -Confirm:$false