Hey,
You can quite easily achieve this by using virtual switch tagging; and trunking to the physical switch.
Create a vSwitch with 2 portgroups. Each portgroup with a different VLAN ID.
Configure the correct vmnic# onto the vSwitch.
Trunk the 2 VLANs onto that vmnic#
Place each vNic onto the 2 portgroups.
Obviously you'll be using VLAN segregation between your DMZ and other network(s)... whether this is within your security policies, you'll need to check.
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~y
If you found this or any other answer useful please consider the use of the Helpful or correct buttons to award points
~y