When I login to Horizon View, it shows me the list of desktops to connect to. If I'm entitled to only one desktop then can View auto connect me to that desktop instead of me clicking on Connect.
Yes you certainly can.
Right click any desktop in the list > Settings > in the left pane select the desktop you want to auto connect to > check "Auto connect to this desktop".
yes, it should work. one further question, if set many desktop as auto-connect, will one click auto-connect to all these desktop at once?
thanks/
