I assume you use VLANs in your network.
If you want to have the internal MSCS network (heartbeat) on separate physical NICs you may create an additional port group on the management/vMotion vSwitch for it and assign a dedicated (unrouted) VLAN-ID to it.
Example:
vSwitch0: vmnic0 + vmnic2 (one onboard and one Mezzanine port)
port group 1: Management Network - Management VLAN - vmnic0 active, vmnic2 standby
port group 2: vMotion - vMotion VLAN - vmnic2 active, vmnic0 standby
port group 3: VM Network - MSCS heartbeat VLAN - vmnic0 active, vmnic2 standby
vSwitch1: vmnic 1 + vmnic3 (one onboard and one Mezzanine port)
port group 1 -n: VM Network - VLAN n - all vmnics active
André