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No VMware Workstation has no PCI passthrough support so that will not work.
For the use case that you are mentioning however there is an existing workaround.
Checkout Darius his description on how-to do this here:
Wil| Author of Vimalin. The virtual machine Backup app for VMware Desktop Products
| Vimalin : Automated backups for VMware Fusion and VMware Workstation Professional
| More info at https://www.vimalin.com
| Twitter @wilva
| VMware Wiki at http://www.vi-toolkit.com