Below are the commands from the latest RCLI. If you've using ESX scripting a fair bit you might consider this insufficient, but if you're new to ESX then the list is pretty sufficient. There are also a number of perl scripts included for managing hosts and VMs.
Do you have any specific scripting needs in mind?
esxcfg-vmhbadevs.pl vicfg-nics.pl
esxcfg-vmknic.pl vicfg-ntp.pl
esxcfg-advcfg.pl esxcfg-vswitch.pl vicfg-rescan.pl
esxcfg-cfgbackup.pl vicfg-route.pl
esxcfg-dns.pl EULA vicfg-snmp.pl
esxcfg-dumppart.pl EULA.rtf vicfg-syslog.pl
esxcfg-module.pl iconv.dll vicfg-user.pl
esxcfg-mpath.pl libxml2.dll vicfg-vmhbadevs.pl
esxcfg-nas.pl svmotion.pl vicfg-vmknic.pl
esxcfg-nics.pl vicfg-advcfg.pl vicfg-vswitch.pl
esxcfg-ntp.pl vicfg-cfgbackup.pl vifs.pl
esxcfg-rescan.pl vicfg-dns.pl vihostupdate.pl
esxcfg-route.pl vicfg-dumppart.pl vmkfstools.pl
esxcfg-snmp.pl vicfg-module.pl vmkuptime.pl
esxcfg-syslog.pl vicfg-mpath.pl vmware-cmd.pl
esxcfg-user.pl vicfg-nas.pl